Depolymerization and Functionalization of Super Engineering Plastics
REVIEW|Updated:2024-11-08
|
Depolymerization and Functionalization of Super Engineering Plastics
Chinese Journal of Polymer ScienceVol. 42, Pages: 1-11(2024)
Affiliations:
a.Hainan Institute of East China Normal University, State Key Laboratory of Petroleum Molecular & Process Engineering, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China
b.Hainan Institute of East China Normal University, State Key Laboratory of Estuarine and Coastal Research, East China Normal University, Shanghai 200241, China
c.State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
Gu, B.; Huang, R.; Zhao, Y.; Jiang, X. Depolymerization and functionalization of super engineering plastics. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-024-3226-1
Boning Gu, Rui Huang, Yinsong Zhao, et al. Depolymerization and Functionalization of Super Engineering Plastics. [J/OL]. Chinese Journal of Polymer Science, 2024,421-11.
Gu, B.; Huang, R.; Zhao, Y.; Jiang, X. Depolymerization and functionalization of super engineering plastics. Chinese J. Polym. Sci. https://doi.org/10.1007/s10118-024-3226-1DOI:
Boning Gu, Rui Huang, Yinsong Zhao, et al. Depolymerization and Functionalization of Super Engineering Plastics. [J/OL]. Chinese Journal of Polymer Science, 2024,421-11. DOI: 10.1007/s10118-024-3226-1.
Depolymerization and Functionalization of Super Engineering Plastics
Chemical recycling/upcycling of plastics has emerged as one of the most promising strategies for the plastic circular economy
enabling the depolymerization and functionalization of plastics into valuable monomers and chemicals. However
studies on the depolymerization and functionalization of challenging super engineering plastics have remained in early stage and underexplored. In this review
we would like to discuss the representative accomplishments and mechanism insights on chemical protocols achieved in depolymerization of super engineering plastics
especially for poly(phenylene sulfide) (PPS)
poly(aryl ether)s including poly(ether ether ketone) (PEEK)
polysulfone (PSU)
polyphenylsulfone (PPSU) and polyethersulfone (PES). We anticipate that this review will provide an overall perspective on the current status and future trends of this emerging field.
关键词
Keywords
Super engineering plasticsChemical recycling/upcyclingDepolymerizationFunctionalization
references
Shea, J. J. Modern plastics handbookIEEE Electr. Insul. Mag. 2000, 16, 52-53..
Fink, J. K.High Performance Polymers. 2 ed.;Elsevier 2014 ..
Maul, J.; Frushour, B. G.; Kontoff, J. R.; Eichenauer, H.; Ott, K. H.; Schade, C., Polystyrene and Styrene Copolymers. InUllmann's Encyclopedia of Industrial Chemistry, 2007 ..
Park, S. A.; Jeon, H.; Kim, H.; Shin, S. H.; Choy, S.; Hwang, D. S.; Koo, J. M.; Jegal, J.; Hwang, S. Y.; Park, J.; Oh, D. X. Sustainable and recyclable super engineering thermoplastic from biorenewable monomer.Nat. Commun.2019,10, 2601..
Dizman, C.; Tasdelen, M. A.; Yagci, Y. Recent advances in the preparation of functionalized polysulfones.Polym. Int.2013,62, 991−1007..
Thakur, S.; Chaudhary, J.; Sharma, B.; Verma, A.; Tamulevicius, S.; Thakur, V. K. Sustainability of bioplastics: Opportunities and challenges.Curr. Opin. Green Sustainable Chem.2018,13, 68−75..
Hinton, Z. R.; Talley, M. R.; Kots, P. A.; Le, A. V.; Zhang, T.; Mackay, M. E.; Kunjapur, A. M.; Bai, P.; Vlachos, D. G.; Watson, M. P.; Berg, M. C.; Epps, T. H.; Korley, L. T. J. Innovations toward the valorization of plastics waste.Annu. Rev. Mater. Res.2022,52, 249−280..
Sheldon, R. A.; Norton, M. Green chemistry and the plastic pollution challenge: towards a circular economy.Green Chem.2020,22, 6310−6322..
Shen, M.; Huang, W.; Chen, M.; Song, B.; Zeng, G.; Zhang, Y. (Micro)plastic crisis: un-ignorable contribution to global greenhouse gas emissions and climate change.J. Cleaner Prod.2020,254, 120138..
Pathak, P.; Sharma, S.; Ramakrishna, S. Circular transformation in plastic management lessens the carbon footprint of the plastic industry.Mater. Today Sustainability2023,22, 100365..
Rahate, A. S.; Nemade, K. R.; Waghuley, S. A. Polyphenylene sulfide (PPS): state of the art and applications.Rev. Chem. Eng.2013,29, 471−489..
Global Polyphenylene Sulfide (PPS) Market fromGlobal Information. https://www.giiresearch.com/report/kbv1450432-global-polyphenylene-sulfide-pps-market-size-share.html (accessed 31 July 2024).
Yu, Z.; Miao, G.; Wu, Q.; Chen, Y. Synthesis of thiol- and carboxyl-terminated poly(p-phenylene sulfide) oligomers.Macromol. Chem. Phys.1996,197, 4061−4068..
Wang, S. J.; Bian, S. G.; Yan, H.; Xiao, M.; Meng, Y. Z. Novel synthesis of macrocyclic disulfides from poly(phenylene sulfide) by depolymerization reaction.J. Appl. Polym. Sci.2008,110, 4049−4054..
Lian, Z.; Bhawal, B. N.; Yu, P.; Morandi, B. Palladium-catalyzed carbon-sulfur or carbon-phosphorus bond metathesis by reversible arylation.Science2017,356, 1059−1063..
Matsuyama, T.; Yatabe, T.; Yabe, T.; Yamaguchi, K. Direct thioether metathesis enabled by in situ formed Pd nanocluster catalysts.Catal. Sci. Technol.2024,14, 76−82..
Matsuyama, T.; Yatabe, T.; Yabe, T.; Yamaguchi, K. Heterogeneously catalyzed thioether metathesis by a supported Au–Pd alloy nanoparticle design based on Pd ensemble control.Chem. Sci. 2024 ..
Delcaillau, T.; Woenckhaus-Alvarez, A.; Morandi, B. Nickel-catalyzed cyanation of aryl thioethers.Org. Lett.2021,23, 7018−7022..
Nakajima, Y.; Minami, Y.; Matsuyama, N.; Matsuo, Y.; Tamura, M.; Sato, K. Catalytic reductive cleavage of poly(phenylene sulfide) using a hydrosilane.Synthesis2021,53, 3351−3354..
El-Hibri, M. J.; Shari, W. A., Polyarylethersulfones. InHandbook of Thermoplastics, Olagoke Olabisi , K. A., Ed. CRC Press: 2015 ..
Minami, Y.; Inagaki, Y.; Tsuyuki, T.; Sato, K.; Nakajima, Y. Hydroxylation-depolymerization of oxyphenylene-based super engineering plastics to regenerate arenols.JACS Au2023,3, 2323−2332..
Marzo, L.; Pagire, S. K.; Reiser, O.; König, B. Visible-light photocatalysis: does it make a difference in organic synthesis.Angew. Chem. In. Ed.2018,57, 10034−10072..
Zhao, Y.; Li, D.; Jiang, X. Chemical upcycling of polyolefins through C−H functionalization.Eur. J. Org. Chem.2023,26, e202300664..
Meng, J.; Zhou, Y.; Li, D.; Jiang, X. Degradation of plastic wastes to commercial chemicals and monomers under visible light.Sci. Bull.2023,68, 1522−1530..
Minami, Y.; Honobe, R.; Inagaki, Y.; Sato, K.; Yoshida, M. Alcoholysis of oxyphenylene-based super engineering plastics mediated by readily available bases.Polym. J.2024,56, 369−377..
Minami, Y.; Imamura, S.; Matsuyama, N.; Nakajima, Y.; Yoshida, M. Catalytic thiolation-depolymerization-like decomposition of oxyphenylene-type super engineering plasticsviaselective carbon–oxygen main chain cleavages.Commun. Chem.2024,7, 37..
Thiruchitrambalam, M.; Bubesh Kumar, D.; Shanmugam, D.; Jawaid, M. A review on PEEK composites – manufacturing methods, properties and applications.Mater. Today:. Proc.2020,33, 1085−1092..
Minami, Y.; Matsuyama, N.; Takeichi, Y.; Watanabe, R.; Mathew, S.; Nakajima, Y. Depolymerization of robust polyetheretherketone to regenerate monomer units using sulfur reagents.Commun. Chem.2023,6, 14..
Graphene Fibers: Advancing Applications in Sensor, Energy Storage and Conversion
Efficient Side-chain Modification of Dextran via Base-catalyzed Epoxide Ring-opening and Thiol-ene Click Chemistry in Aqueous Media
PARTIAL CARBAMOYLATION OF CELLULOSE MICROSPHERES: A NEW METHOD TO PREPARE ADSORBENTS FOR LIQUID CHROMATOGRAPHY
Related Author
Guan-Hang Yu
Qing Han
Liang-Ti Qu
Ming-qiang Li
Zhao-hui Tang
Chao Wang
Yu Zhang
Hai-tao Cui
Related Institution
Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Key Laboratory of Cluster Science Ministry of Education, School of Chemistry, Beijing Institute of Technology
Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences
School of Science, Changchun institute of technology
University of Chinese Academy of Sciences
Key Lab for Large-Format Battery Materials and Systems, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology