a.College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, China
b.National Engineering Laboratory for Modern Silk, Suzhou 215123, China
yantao@suda.edu.cn (T.Y.)
zhjpan@suda.edu.cn (Z.J.P)
Scan for full text
Shi-Dong Ma, Yu-Ting Wu, Jian Tang, et al. A Multi-model, Large-range Flexible Strain Sensor Based on Carbonized Silk Habotai for Human Health Monitoring. [J]. Chinese Journal of Polymer Science 41(8):1238-1249(2023)
Shi-Dong Ma, Yu-Ting Wu, Jian Tang, et al. A Multi-model, Large-range Flexible Strain Sensor Based on Carbonized Silk Habotai for Human Health Monitoring. [J]. Chinese Journal of Polymer Science 41(8):1238-1249(2023) DOI: 10.1007/s10118-023-2924-4.
In recent years, flexible strain sensors have received considerable attention owing to their excellent flexibility and multifunctionality. However, it is still a great challenge for them to accurately monitor multi-model deformations with high sensitivity and linearity. In this study, the industrial insulating silk habotai was successfully converted into carbonized silk habotai (CSH) for use in strain sensors. A strain sensor created using CSH exhibited excellent sensing performance under multi-model deformations, including stretching, twist and bending. The maximum tensile strain was 434%. The gauge factors were 14.6 in the wide tensile range of 0%–400% with a high linearity of 0.959. In addition, the CSH strain sensor exhibited an extremely fast response time (110 ms) and could accurately detect bending (0°–180°) and torsional (0°–180°) strains. High durability and repeatability were observed for the multi-model strains. Finally, a new type of smart pillow was developed to accurately record head movement and breathing during sleep. The sensor may also be used for auxiliary training in table tennis. The proposed CSH strain sensor has shown great potential for applications in smart devices and human-machine interactions.
Carbonized silk habotaiStrain sensorSmart pillowHuman motions
Amjadi,M.;Kyung,K.U.;Park,I.;Sitti,M.Stretchable,skin-mountable,andwearablestrainsensorsandtheirpotentialapplications:areview.Adv. Funct. Mater.2016,26,1678−1698..
Wu,Y.T.;Yan,T.;Pan,Z.J.Wearablecarbon-basedresistivesensorsforstraindetection:areview.IEEE Sens. J.2021,21,4030−4043..
Goldoni,R.;Ozkan-Aydin,Y.;Kim,Y.S.;Kim,J.;Zavanelli,N.;Mahmood,M.;Liu,B.;Hammond,F.L.,3rd;Goldman,D.I.;Yeo,W.H.Stretchablenanocompositesensors,nanomembraneinterconnectors,andwirelesselectronicstowardfeedback-loopcontrolofasoftearthwormrobot.ACS Appl. Mater. Interfaces2020,12,43388−43397..
Zhang,M.;Wang,C.;Wang,Q.;Jian,M.;Zhang,Y.Sheath-coregraphite/silkfibermadebydry-meyer-rod-coatingforwearablestrainsensors.ACS Appl. Mater. Interfaces2016,8,20894−20899..
Hang,C.Z.;Zhao,X.F.;Xi,S.Y.;Shang,Y.H.;Yuan,K.P.;Yang,F.;Wang,Q.G.;Wang,J.C.;Zhang,D.W.;Lu,H.L.Highlystretchableandself-healingstrainsensorsformotiondetectioninwirelesshuman-machineinterface.Nano Energy2020,76,105064..
Tian,H.;Shu,Y.;Cui,Y.L.;Mi,W.T.;Yang,Y.;Xie,D.;Ren,T.L.Scalablefabricationofhigh-performanceandflexiblegraphenestrainsensors.Nanoscale2014,6,699−705..
Yan,T.;Wu,Y.;Pan,Z.Anisotropyofresistance-typestrainsensingnetworksbasedonalignedcarbonnanofibermembrane.J Mater. Sci.2021,56,6292−6305..
Zhao,M.;Li,D.;Huang,J.;Wang,D.;Mensah,A.;Wei,Q.Amultifunctionalandhighlystretchableelectronicdevicebasedonsilvernanowire/wrapyarncompositeforawearablestrainsensorandheater.J. Mater. Chem. C2019,7,13468−13476..
Zhang,J.;Wan,L.;Gao,Y.;Fang,X.;Lu,T.;Pan,L.;Xuan,F.Highlystretchableandself-healablemxene/polyvinylalcoholhydrogelelectrodeforwearablecapacitiveelectronicskin.Adv. Electron. Mater.2019,5,1900285..
Cai,L.;Song,L.;Luan,P.;Zhang,Q.;Zhang,N.;Gao,Q.;Zhao,D.;Zhang,X.;Tu,M.;Yang,F.;Zhou,W.;Fan,Q.;Luo,J.;Zhou,W.;Ajayan,P.M.;Xie,S.Super-stretchable,transparentcarbonnanotube-basedcapacitivestrainsensorsforhumanmotiondetection.Sci. Rep.2013,3,3048..
Yang,J.C.;Kim,J.O.;Oh,J.;Kwon,S.Y.;Sim,J.Y.;Kim,D.W.;Choi,H.B.;Park,S.Microstructuredporouspyramid-basedultrahighsensitivepressuresensorinsensitivetostrainandtemperature.ACS Appl. Mater. Interfaces2019,11,19472−19480..
Liu,Y.;Hu,Y.;Zhao,J.;Wu,G.;Tao,X.;Chen,W.Self-poweredpiezoionicstrainsensortowardthemonitoringofhumanactivities.Small2016,12,5074−5080..
Qian,S.;Qin,L.;He,J.;Zhang,N.;Qian,J.;Mu,J.;Geng,W.;Hou,X.;Chou,X.Alead-freestretchablepiezoelectriccompositeforhumanmotionmonitoring.Mater. Lett.2020,261,127119..
Meng,B.;Tang,W.;Too,Z.H.;Zhang,X.;Han,M.;Liu,W.;Zhang,H.Atransparentsingle-friction-surfacetriboelectricgeneratorandself-poweredtouchsensor.Energy Environ. Sci.2013,6,3235−3240..
Wang,S.H.;Lin,L.;Wang,Z.L.Triboelectricnanogeneratorsasself-poweredactivesensors.Nano Energy2015,11,436−462..
Gao,Y.;Guo,F.;Cao,P.;Liu,J.;Li,D.;Wu,J.;Wang,N.;Su,Y.;Zhao,Y.Winding-lockedcarbonnanotubes/polymernanofibershelicalyarnforultrastretchableconductorandstrainsensor.ACS Nano2020,14,3442−3450..
Ding,L.;Xuan,S.;Feng,J.;Gong,X.Magnetic/conductivecompositefiber:amultifunctionalstrainsensorwithmagneticallydrivenproperty.Compos. Part A2017,100,97−105..
Tang,J.;Wu,Y.;Ma,S.;Yan,T.;Pan,Z.FlexiblestrainsensorbasedonCNT/TPUcompositenanofiberyarnforsmartsportsbandage.Compos. Part B Eng.2022,232,109605..
Ma,S.D.;Tang,J.;Yan,T.;Pan,Z.J.Performanceofflexiblestrainsensorswithdifferenttransitionmechanisms:areview.IEEE Sens. J.2022,22,7475−7498..
Tang,J.;Wu,Y.;Ma,S.;Yan,T.;Pan,Z.Strain-sensingcompositenanofiberfilamentandregulationmechanismofshoulderpeaksbasedoncarbonnanomaterialdispersion.ACS Appl. Mater. Interfaces2023,15,7329−7404..
Wu,Y.;Yan,T.;Zhang,K.;Pan,Z.Ahollowcore-sheathcompositefiberbasedonpolyaniline/polyurethane:preparation,properties,andmulti-modelstrainsensingperformance.Adv. Mater. Technol.2023,8,2200777..
Park,J.J.;Hyun,W.J.;Mun,S.C.;Park,Y.T.;Park,O.O.Highlystretchableandwearablegraphenestrainsensorswithcontrollablesensitivityforhumanmotionmonitoring.ACS Appl. Mater. Interfaces2015,7,6317−6324..
Cai,Y.;Shen,J.;Ge,G.;Zhang,Y.;Jin,W.;Huang,W.;Shao,J.;Yang,J.;Dong,X.StretchableTi3C2TxMXene/carbonnanotubecompositebasedstrainsensorwithultrahighsensitivityandtunablesensingrange.ACS Nano2018,12,56−62..
Yee,M.J.;Mubarak,N.M.;Abdullah,E.C.;Khalid,M.;Walvekar,R.;Karri,R.R.;Nizamuddin,S.;Numan,A.Carbonnanomaterialsbasedfilmsforstrainsensingapplication-areview.Nano-Struct. Nano-Object2019,18,100312..
Huang,J.;Li,D.;Zhao,M.;Mensah,A.;Lv,P.;Tian,X.;Huang,F.;Ke,H.;Wei,Q.HighlysensitiveandstretchableCNT-bridgedAgNPstrainsensorbasedonTPUelectrospunmembraneforhumanmotiondetection.Adv. Electron. Mater.2019,1900241,5..
Sang,S.;Liu,L.;Jian,A.;Duan,Q.;Ji,J.;Zhang,Q.;Zhang,W.Highlysensitivewearablestrainsensorbasedonsilvernanowiresandnanoparticles.Nanotechnology2018,29,255202..
Li,M.;Li,H.;Zhong,W.;Zhao,Q.;Wang,D.Stretchableconductivepolypyrrole/polyurethane(PPy/PU)strainsensorwithnetlikemicrocracksforhumanbreathdetection.ACS Appl. Mater. Interfaces2014,6,1313−1319..
Gong,X.X.;Fei,G.T.;Fu,W.B.;Fang,M.;Gao,X.D.;Zhong,B.N.;Zhang,L.D.FlexiblestrainsensorwithhighperformancebasedonPANI/PDMSfilms.Org. Electron.2017,47,51−56..
Jia,Y.;Shen,L.;Liu,J.;Zhou,W.;Du,Y.;Xu,J.;Liu,C.;Zhang,G.;Zhang,Z.;Jiang,F.AnefficientPEDOT-coatedtextileforwearablethermoelectricgeneratorsandstrainsensors.J. Mater. Chem. C2019,7,3496−3502..
TranQuang,T.;Lee,N.E.Flexibleandstretchablephysicalsensorintegratedplatformsforwearablehuman-activitymonitoringandpersonalhealthcare.Adv. Mater.2016,28,4338−4372..
Tang,J.;Wu,Y.;Ma,S.;Yan,T.;Pan,Z.Sensingmechanismofaflexiblestrainsensordevelopeddirectlyusingelectrospuncompositenanofiberyarnwithternarycarbonnanomaterials.iScience2022,25,105162..
Ma,D.L.;Ma,Y.;Chen,Z.W.;Hu,A.M.Asilkfabricderivedcarbonfibrenetfortransparentcapacitivetouchpadsandall-solidsupercapacitors.J. Mater. Chem. A2017,5,20608−20614..
Pan,P.;Hu,Y.;Wu,K.;Cheng,Z.;Shen,Z.;Jiang,L.;Mao,J.;Ni,C.;Ge,Y.;Wang,Z.GrowthofZnCo2O4nanocubesonflexiblebiocharsubstratederivedfromnaturalsilkwastefabricforlithium-ionbatteryanode.J. Alloys. Compd.2020,814,152306..
Li,X.;Zhao,J.;Cai,Z.;Ge,F.Free-standingcarbonelectrodematerialswiththree-dimensionalhierarchicallyporousstructurederivedfromwastedyedsilkfabrics.Mater. Res. Bull.2018,107,355−360..
Li,X.;Sun,C.;Cai,Z.;Ge,F.High-performanceall-solid-statesupercapacitorderivedfromPPycoatedcarbonizedsilkfabric.Appl. Surf. Sci.2019,473,967−975..
Chen,C.;Ran,R.;Yang,Z.;Lv,R.;Shen,W.;Kang,F.;Huang,Z.H.Anefficientflexibleelectrochemicalglucosesensorbasedoncarbonnanotubes/carbonizedsilkfabricsdecoratedwithPtmicrospheres.Sens. Actuators B2018,256,63−70..
Ji,W.;Wu,D.;Tang,W.;Xi,X.;Su,Y.;Guo,X.;Liu,R.Carbonizedsilkfabric-basedflexibleorganicelectrochemicaltransistorsforhighlysensitiveandselectivedopaminedetection.Sens. Actuators B2020,304,127414..
Martel,A.;Burghammer,M.;Davies,R.J.;Riekel,C.Thermalbehaviorofbombyxmorisilk:evolutionofcrystallineparameters,molecularstructure,andmechanicalproperties.Biomacromolecules2007,8,3548−3556..
Xiong,X.;Tang,Y.;Xu,C.;Huang,Y.;Wang,Y.;Fu,L.;Lin,C.;Zhou,D.;Lin,Y.Highcarbonizationtemperaturetotriggerenzymemimickingactivitiesofsilk-derivednanosheets.Small2020,16,e2004129..
Li,X.;Zhao,J.;Cai,Z.;Ge,F.Adyeing-inducedheteroatom-co-dopedroutetowardflexiblecarbonelectrodederivedfromsilkfabric.J. Mater. Sci.2018,53,7735−7743..
Hu,M.;Hu,T.;Cheng,R.;Yang,J.;Cui,C.;Zhang,C.;Wang,X.MXene-coatedsilk-derivedcarbonclothtowardflexibleelectrodeforsupercapacitorapplication.J. Energy Chem.2018,27,161−166..
Huang,P.;Yu,X.G.;Li,Y.Q.;Fu,Y.F.;Gan,D.M.;Taha,T.;Fu,Y.Q.;Hu,N.;Fu,S.Y.Architecturaldesignofflexibleanisotropicpiezoresistivecompositeformultiple-loadingrecognization.Compos. B. Eng.2020,182,107631..
Deng,C.;Pan,L.;Cui,R.;Li,C.;Qin,J.Wearablestrainsensormadeofcarbonizedcottoncloth.J. Mater. Sci.: Mater. Electron.2016,28,3535−3541..
Liu,Z.;Chen,K.;Fernando,A.;Gao,Y.;Li,G.;Jin,L.;Zhai,H.;Yi,Y.;Xu,L.;Zheng,Y.;Li,H.;Fan,Y.;Li,Y.;Zheng,Z.Permeablegraphitedhempfabrics-based,wearing-comfortablepressuresensorsformonitoringhumanactivities.Chem. Eng. J.2021,403,126191..
Liang,J.J.;Zhao,Z.B.;Tang,Y.C.;Liang,Z.H.;Sun,L.L.;Pan,X.;Wang,X.Z.;Qiu,J.S.Awearablestrainsensorbasedoncarbonderivedfromlinenfabrics.New Carbon Mater.2020,35,522−530..
Wang,C.;Zhang,M.;Xia,K.;Gong,X.;Wang,H.;Yin,Z.;Guan,B.;Zhang,Y.Intrinsicallystretchableandconductivetextilebyascalableprocessforelasticwearableelectronics.ACS Appl. Mater. Interfaces2017,9,13331−13338..
Zhang,M.;Wang,C.;Wang,H.;Jian,M.;Hao,X.;Zhang,Y.Carbonizedcottonfabricforhigh-performancewearablestrainsensors.Adv. Funct. Mater.2017,27,1604795..
Yan,T.;Zhou,H.;Niu,H.;Shao,H.;Wang,H.;Pan,Z.;Lin,T.Highlysensitivedetectionofsubtlemovementusingaflexiblestrainsensorfromhelicallywrappedcarbonyarns.J. Mater. Chem. C2019,7,10049−10058..
Wang,C.;Xia,K.;Jian,M.;Wang,H.;Zhang,M.;Zhang,Y.Carbonizedsilkgeorgetteasanultrasensitivewearablestrainsensorforfull-rangehumanactivitymonitoring.J. Mater. Chem. C2017,5,7604−7611..
Wang,C.;Li,X.;Gao,E.;Jian,M.;Xia,K.;Wang,Q.;Xu,Z.;Ren,T.;Zhang,Y.Carbonizedsilkfabricforultrastretchable,highlysensitive,andwearablestrainsensors.Adv. Mater.2016,28,6640−6648..
Chen,Z.;Yan,T.;Pan,Z.Reviewofflexiblestrainsensorsbasedoncellulosecompositesformulti-facetedapplications.Cellulose2021,28,615−645..
Rousseau,M.E.;Lefevre,T.;Beaulieu,L.;Asakura,T.;Pezolet,M.StudyofProteinconformationandorientationinsilkwormandspidersilkfibersusingRamanmicrospectroscopy.Biomacromolecules2004,5,2247−2257..
Belin,T.;Epron,F.Characterizationmethodsofcarbonnanotubes:areview.J. Mater. Sci. Eng. B2005,119,105−118..
Atchudan,R.;Edison,T.N.J.I.;Chakradhar,D.;Perumal,S.;Shim,J.J.;Lee,Y.R.Facilegreensynthesisofnitrogen-dopedcarbondotsusingchionanthusretususfruitextractandinvestigationoftheirsuitabilityformetalionsensingandbiologicalapplications.Sens. Actuators B2017,246,497−509..
0
Views
9
Downloads
0
CSCD
Publicity Resources
Related Articles
Related Author
Related Institution