3-Methylcyclohexanone Processed n-Channel Organic Thin-Film Transistors Based on a Conjugated Polymer Synthesized by Direct Arylation Polycondensation

Dong-Sheng Yan; Xu-Wen Zhang; Zhong-Li Wang; Chen-Hui Xu; Yi-Bo Shi; Yun-Feng Deng; Yang Han; Yan-Hou Geng

doi:10.1007/s10118-023-2937-z

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3-Methylcyclohexanone Processed n-Channel Organic Thin-Film Transistors Based on a Conjugated Polymer Synthesized by Direct Arylation Polycondensation

RESEARCH ARTICLE | Updated：2023-04-21

- 3-Methylcyclohexanone Processed n-Channel Organic Thin-Film Transistors Based on a Conjugated Polymer Synthesized by Direct Arylation Polycondensation
- Chinese Journal of Polymer Science Vol. 41, Issue 5, Pages: 824-831(2023)
- Affiliations：
  
  a.School of Materials Science and Engineering and Tianjin Key Laboratory of Molecular Optoelectronic Science, Tianjin University, and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, China
  b.State Key Laboratory of Separation Membranes and Membrane Processes, Tianjin Key Laboratory of Advanced Fibers and Energy Storage, School of Material Science and Engineering, Tiangong University, Tianjin 300387, China
  c.Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Fuzhou 350207, China
- Author bio：
  
  zhongliwang@tiangong.edu.cn(Z.L.W.)
  yanhou.geng@tju.edu.cn (Y.H.G.)
- Funds：
- DOI：10.1007/s10118-023-2937-z
  CLC：
- Received：21 November 2022，
  
  Revised：2022-12-22，
  
  Accepted：23 December 2022，
  
  Online First：21 February 2023，
  
  Published：01 May 2023
- Accepted：
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Yan, D. S.; Zhang, X. W.; Wang, Z. L.; Xu, C. H.; Shi, Y. B.; Deng, Y. F.; Han, Y.; Geng, Y. H. 3-Methylcyclohexanone processed n-channel organic thin-film transistors based on a conjugated polymer synthesized by direct arylation polycondensation.Chinese J. Polym. Sci.2023,41, 824–831

Dong-Sheng Yan, Xu-Wen Zhang, Zhong-Li Wang, et al. 3-Methylcyclohexanone Processed n-Channel Organic Thin-Film Transistors Based on a Conjugated Polymer Synthesized by Direct Arylation Polycondensation[J]. Chinese Journal of Polymer Science, 2023, 41(5): 824-831.
Yan, D. S.; Zhang, X. W.; Wang, Z. L.; Xu, C. H.; Shi, Y. B.; Deng, Y. F.; Han, Y.; Geng, Y. H. 3-Methylcyclohexanone processed n-channel organic thin-film transistors based on a conjugated polymer synthesized by direct arylation polycondensation.Chinese J. Polym. Sci.2023,41, 824–831 DOI： 10.1007/s10118-023-2937-z.

Dong-Sheng Yan, Xu-Wen Zhang, Zhong-Li Wang, et al. 3-Methylcyclohexanone Processed n-Channel Organic Thin-Film Transistors Based on a Conjugated Polymer Synthesized by Direct Arylation Polycondensation[J]. Chinese Journal of Polymer Science, 2023, 41(5): 824-831. DOI： 10.1007/s10118-023-2937-z.

摘要

Direct arylation polycondensation synthesized conjugated polymer PFuDPP-4FTVT is soluble in 3-methylcyclohexanone (3-MC). n-Channel organic thin-film transistors of the polymer with electron mobility (

) above 1 cm

·V

−1

·s

−1

were fabricated with 3-MC. This is the first report on high mobility conjugated polymers processible with naturally occurred green solvent.

Abstract

The solubility of a direct arylation polycondensation (DArP) synthesized conjugated polymer

i.e.

poly(3

6-bis(furan-2-yl)-2

5-bis(4-tetradecyloctadecyl)-pyrrolo[3

]pyrrole-1

4(2

)-dione-

alt

-1

2-bis(3

4-difluorothien-2-yl)ethene) (PFuDPP-4FTVT)

in various organic solvents was studied. The polymer is soluble in 3-methylcyclohexanone (3-MC)

a green solvent from peppermint oil

besides other solvents such as anisole

cyclopentyl methyl ether (CPME) and

-dichlorobenzene (

-DCB)

etc

. Based on the Hansen solubility parameters (HSP) analysis

3-MC is identified as a “marginal solvent” of PFuDPP-4FTVT. The morphology of the spin-coated films with 3-MC as the solvent strongly correlated with the solution preparation conditions. With a 3-MC solution aged for 3 h at 70 °C

n-channel organic thin-film transistors (OTFTs) with electron mobility (

) above 1 cm

·V

−1

·s

−1

and current on/off ratio (

off

) higher than 10

were fabricated by spin-coating. This is the first report on high mobility conjugated polymers for OTFTs processible with naturally occurred green solvent.

关键词

Keywords

references

Huang, F.; Bo, Z. S.; Geng, Y. H.; Wang, X. H.; Wang, L. X.; Ma, Y. G.; Hou, J. H.; Hu, W. P.; Pei, J.; Dong, H. L.; Wang, S.; Li, Z.; Shuai, Z. G.; Li, Y. F.; Cao, Y . Study on optoelectronic polymers: an overview and outlook . Acta Polymerica Sinica (in Chinese) , 2019 , 50 988 - 1046 . DOI: 10.11777/j.issn1000-3304.2019.19110 http://doi.org/10.11777/j.issn1000-3304.2019.19110 .

Kim, M.; Ryu, S. U.; Park, S. A.; Choi, K.; Kim, T.; Chung, D.; Park, T . Donor-acceptor-conjugated polymer for high-performance organic field-effect transistors: a progress report . Adv. Funct. Mater. , 2019 , 30 1904545 .

Zhou, Y.; Zhang, W.; Yu, G . Recent structural evolution of lactam- and imide-functionalized polymers applied in organic field-effect transistors and organic solar cells . Chem. Sci. , 2021 , 12 6844 - 6878 . DOI: 10.1039/D1SC01711J http://doi.org/10.1039/D1SC01711J .

Chen, J.; Yang, J.; Guo, Y.; Liu, Y . Acceptor modulation strategies for improving the electron transport in high-performance organic field-effect transistors . Adv. Mater. , 2022 , 34 e2104325 DOI: 10.1002/adma.202104325 http://doi.org/10.1002/adma.202104325 .

Liu, Q.; Bottle, S. E.; Sonar, P . Developments of diketopyrrolopyrrole-dye-based organic semiconductors for a wide range of applications in electronics . Adv. Mater. , 2020 , 32 e1903882 DOI: 10.1002/adma.201903882 http://doi.org/10.1002/adma.201903882 .

Yang, Y.; Liu, Z.; Zhang, G.; Zhang, X.; Zhang, D . The effects of side chains on the charge mobilities and functionalities of semiconducting conjugated polymers beyond solubilities . Adv. Mater. , 2019 , 31 e1903104 DOI: 10.1002/adma.201903104 http://doi.org/10.1002/adma.201903104 .

Nielsen, C. B.; Turbiez, M.; McCulloch, I . Recent advances in the development of semiconducting DPP-containing polymers for transistor applications . Adv. Mater. , 2013 , 25 1859 - 1880 . DOI: 10.1002/adma.201201795 http://doi.org/10.1002/adma.201201795 .

Shen, T.; Li, W.; Zhao, Y.; Liu, Y.; Wang, Y . An all-C–H-activation strategy to rapidly synthesize high-mobility well-balanced ambipolar semiconducting polymers . Matter , 2022 , 5 1953 - 1968 . DOI: 10.1016/j.matt.2022.04.008 http://doi.org/10.1016/j.matt.2022.04.008 .

Kang, I.; Yun, H. J.; Chung, D. S.; Kwon, S. K.; Kim, Y. H . Record high hole mobility in polymer semiconductors via side-chain engineering . J. Am. Chem. Soc. , 2013 , 135 14896 - 14899 . DOI: 10.1021/ja405112s http://doi.org/10.1021/ja405112s .

Yao, J.; Yu, C.; Liu, Z.; Luo, H.; Yang, Y.; Zhang, G.; Zhang, D . Significant improvement of semiconducting performance of the diketopyrrolopyrrole-quaterthiophene conjugated polymer through side-chain engineering via hydrogen-bonding . J. Am. Chem. Soc. , 2016 , 138 173 - 185 . DOI: 10.1021/jacs.5b09737 http://doi.org/10.1021/jacs.5b09737 .

Wang, Z.; Gao, M.; He, C.; Shi, W.; Deng, Y.; Han, Y.; Ye, L.; Geng, Y . Unraveling the molar mass dependence of shearing-induced aggregation structure of a high-mobility polymer semiconductor . Adv. Mater. , 2022 , 34 e2108255 DOI: 10.1002/adma.202108255 http://doi.org/10.1002/adma.202108255 .

Zhang, A.; Xiao, C.; Wu, Y.; Li, C.; Ji, Y.; Li, L.; Hu, W.; Wang, Z.; Ma, W.; Li, W . Effect of fluorination on molecular orientation of conjugated polymers in high performance field-effect transistors . Macromolecules , 2016 , 49 6431 - 6438 . DOI: 10.1021/acs.macromol.6b01446 http://doi.org/10.1021/acs.macromol.6b01446 .

Back, J. Y.; Yu, H.; Song, I.; Kang, I.; Ahn, H.; Shin, T. J.; Kwon, S. K.; Oh, J. H.; Kim, Y. H . Investigation of structure-property relationships in diketopyrrolopyrrole-based polymer semiconductors via side-chain engineering . Chem. Mater. , 2015 , 27 1732 - 1739 . DOI: 10.1021/cm504545e http://doi.org/10.1021/cm504545e .

Lv, S. Y.; Li, Q. Y.; Li, B. W.; Wang, J. Y.; Mu, Y. B.; Li, L.; Pei, J.; Wan, X. B . Thiazole-flanked thiazoloisoindigo as a monomer for balanced ambipolar polymeric field-effect transistors . Chinese J. Polym. Sci. , 2022 , 40 1131 - 1140 . DOI: 10.1007/s10118-022-2731-3 http://doi.org/10.1007/s10118-022-2731-3 .

Capello, C.; Fischer, U.; Hungerbühler, K . What is a green solvent? A comprehensive framework for the environmental assessment of solvents. . Green Chem. , 2007 , 9 927 - 934 . DOI: 10.1039/b617536h http://doi.org/10.1039/b617536h .

Campana, F.; Kim, C.; Marrocchi, A.; Vaccaro, L . Green solvent-processed organic electronic devices . J. Mater. Chem. C , 2020 , 8 15027 - 15047 . DOI: 10.1039/D0TC03610B http://doi.org/10.1039/D0TC03610B .

Ran, Y.; Guo, Y.; Liu, Y . Organostannane-free polycondensation and eco-friendly processing strategy for the design of semiconducting polymers in transistors . Mater. Horiz. , 2020 , 7 1955 - 1970 . DOI: 10.1039/D0MH00138D http://doi.org/10.1039/D0MH00138D .

Choi, H. H.; Baek, J. Y.; Song, E.; Kang, B.; Cho, K.; Kwon, S.-K.; Kim, Y. H . A pseudo-regular alternating conjugated copolymer using an asymmetric monomer: a high-mobility organic transistor in nonchlorinated solvents . Adv. Mater. , 2015 , 27 3626 - 3631 . DOI: 10.1002/adma.201500335 http://doi.org/10.1002/adma.201500335 .

Ji, Y.; Xiao, C.; Wang, Q.; Zhang, J.; Li, C.; Wu, Y.; Wei, Z.; Zhan, X.; Hu, W.; Wang, Z.; Janssen, R. A. J.; Li, W . Asymmetric diketopyrrolopyrrole conjugated polymers for field-effect transistors and polymer solar cells processed from a nonchlorinated solvent . Adv. Mater. , 2016 , 28 943 - 950 . DOI: 10.1002/adma.201504272 http://doi.org/10.1002/adma.201504272 .

Yun, H. J.; Lee, G. B.; Chung, D. S.; Kim, Y. H.; Kwon, S. K . Novel diketopyrroloppyrrole random copolymers: high charge-carrier mobility from environmentally benign processing . Adv. Mater. , 2014 , 26 6612 - 6616 . DOI: 10.1002/adma.201400877 http://doi.org/10.1002/adma.201400877 .

Ding, S.; Ni, Z.; Hu, M.; Qiu, G.; Li, J.; Ye, J.; Zhang, X.; Liu, F.; Dong, H.; Hu, W . An asymmetric furan/thieno[3,2- b ]thiophene diketopyrrolopyrrole building block for annealing-free green-solvent processable organic thin-film transistors . Macromol. Rapid Commun. , 2018 , 39 e1800225 DOI: 10.1002/marc.201800225 http://doi.org/10.1002/marc.201800225 .

Wang, Z.; Song, X.; Jiang, Y.; Zhang, J.; Yu, X.; Deng, Y.; Han, Y.; Hu, W.; Geng, Y . A simple structure conjugated polymer for high mobility organic thin film transistors processed from nonchlorinated solvent . Adv. Sci. , 2019 , 6 1902412 DOI: 10.1002/advs.201902412 http://doi.org/10.1002/advs.201902412 .

Wang, Z.; Shi, Y.; Deng, Y.; Han, Y.; Geng, Y . Toward high mobility green solvent-processable conjugated polymers: a systematic study on chalcogen effect in poly(diketopyrrolopyrrole- alt -terchalcogenophene)s . Adv. Funct. Mater. , 2021 , 31 2104881 DOI: 10.1002/adfm.202104881 http://doi.org/10.1002/adfm.202104881 .

Ding, Y.; Zhao, F.; Kim, S.; Wang, X.; Lu, H.; Zhang, G.; Cho, K.; Qiu, L . Azaisoindigo-based polymers with a linear hybrid siloxane-based side chain for high-performance semiconductors processable with nonchlorinated solvents . ACS Appl. Mater. Interfaces , 2020 , 12 41832 - 41841 . DOI: 10.1021/acsami.0c11436 http://doi.org/10.1021/acsami.0c11436 .

Ding, Y.; Jiang, L.; Du, Y.; Kim, S.; Wang, X.; Lu, H.; Zhang, G.; Cho, K.; Qiu, L . Linear hybrid siloxane-based side chains for highly soluble isoindigo-based conjugated polymers . Chem. Commun. , 2020 , 56 11867 - 11870 . DOI: 10.1039/D0CC01497D http://doi.org/10.1039/D0CC01497D .

Prat, D.; Wells, A.; Hayler, J.; Sneddon, H.; McElroy, C. R.; Abou-Shehada, S.; Dunn, P. J . CHEM21 selection guide of classical- and less classical-solvents . Green Chem. , 2016 , 18 288 - 296 . DOI: 10.1039/C5GC01008J http://doi.org/10.1039/C5GC01008J .

Alder, C. M.; Hayler, J. D.; Henderson, R. K.; Redman, A. M.; Shukla, L.; Shuster, L. E.; Sneddon, H. F . Updating and further expanding GSK's solvent sustainability guide . Green Chem. , 2016 , 18 3879 - 3890 . DOI: 10.1039/C6GC00611F http://doi.org/10.1039/C6GC00611F .

Prat, D.; Pardigon, O.; Flemming, H.-W.; Letestu, S.; Ducandas, V.; Isnard, P.; Guntrum, E.; Senac, T.; Ruisseau, S.; Cruciani, P.; Hosek, P . Sanofi’s solvent selection guide: a step toward more sustainable processes . Org. Process Res. Dev. , 2013 , 17 1517 - 1525 . DOI: 10.1021/op4002565 http://doi.org/10.1021/op4002565 .

Alfonsi, K.; Colberg, J.; Dunn, P. J.; Fevig, T.; Jennings, S.; Johnson, T. A.; Kleine, H. P.; Knight, C.; Nagy, M. A.; Perry, D. A.; Stefaniak, M . Green chemistry tools to influence a medicinal chemistry and research chemistry based organisation . Green Chem. , 2008 , 10 31 - 36 . DOI: 10.1039/B711717E http://doi.org/10.1039/B711717E .

Chen, M. S.; Lee, O. P.; Niskala, J. R.; Yiu, A. T.; Tassone, C. J.; Schmidt, K.; Beaujuge, P. M.; Onishi, S. S.; Toney, M. F.; Zettl, A.; Fréchet, J. M. J . Enhanced solid-state order and field-effect hole mobility through control of nanoscale polymer aggregation . J. Am. Chem. Soc. , 2013 , 135 19229 - 19236 . DOI: 10.1021/ja4088665 http://doi.org/10.1021/ja4088665 .

Sonar, P.; Chang, J.; Kim, J. H.; Ong, K. H.; Gann, E.; Manzhos, S.; Wu, J.; McNeill, C. R . High-mobility ambipolar organic thin-film transistor processed from a nonchlorinated solvent . ACS Appl. Mater. Interfaces , 2016 , 8 24325 - 24330 . DOI: 10.1021/acsami.6b08075 http://doi.org/10.1021/acsami.6b08075 .

Lee, S. M.; Lee, H. R.; Han, A. R.; Lee, J.; Oh, J. H.; Yang, C . High-performance furan-containing conjugated polymer for environmentally benign solution processing . ACS Appl. Mater. Interfaces , 2017 , 9 15652 - 15661 . DOI: 10.1021/acsami.7b04014 http://doi.org/10.1021/acsami.7b04014 .

Sui, Y.; Wang, Z.; Bai, J.; Shi, Y.; Zhang, X.; Deng, Y.; Han, Y.; Geng, Y . Diketopyrrolopyrrole-based conjugated polymers synthesized by direct arylation polycondensation for anisole-processed high mobility organic thin-film transistors . J. Mater. Chem. C , 2022 , 10 2616 - 2622 . DOI: 10.1039/D1TC04207F http://doi.org/10.1039/D1TC04207F .

Li, C.; Misovich, M. V.; Pardo, M.; Fang, Z.; Laskin, A.; Chen, J.; Rudich, Y . Secondary organic aerosol formation from atmospheric reactions of anisole and associated health effects . Chemosphere , 2022 , 308 136421 DOI: 10.1016/j.chemosphere.2022.136421 http://doi.org/10.1016/j.chemosphere.2022.136421 .

Snyder, R.; Hedli, C. C . An overview of benzene metabolism . Environ. Health Perspect , 1996 , 104 1165 - 1171 .

Mohaddese M.; Nastaran K . Chemical composition and antimicrobial activity of peppermint (mentha piperita L.) essential oil . Songklanakarin J. Sci. Technol. , 2014 , 36 83 - 87 .

Newberne, P; Doull, J; Feron, V. J.; Goodman, J. I.; Munro, I. C.; Portoghese, P. S.; Waddell, W. J.; Wagner, B. M.; Weil, C. S.; Adams, T. B.; Hallagan, J. B . GRAS flavoring substances 19 . Food Technol. , 2000 , 54 66 - 84 .

Lee, J.; Kim, G. W.; Kim, M.; Park, S. A.; Park, T . Nonaromatic green-solvent-processable, dopant-free, and lead-capturable hole transport polymers in perovskite solar cells with high efficiency . Adv. Energy Mater. , 2020 , 10 1902662 DOI: 10.1002/aenm.201902662 http://doi.org/10.1002/aenm.201902662 .

Machui, F.; Abbott, S.; Waller, D.; Koppe, M.; Brabec, C. J . Determination of Solubility Parameters for organic semiconductor formulations . Macromol. Chem. Phys. , 2011 , 212 2159 - 2165 . DOI: 10.1002/macp.201100284 http://doi.org/10.1002/macp.201100284 .

Kim, N. K.; Shin, E. S.; Noh, Y. Y.; Kim, D. Y . A selection rule of solvent for highly aligned diketopyrrolopyrrole-based conjugated polymer film for high performance organic field-effect transistors . Org. Electron. , 2018 , 55 6 - 14 . DOI: 10.1016/j.orgel.2018.01.006 http://doi.org/10.1016/j.orgel.2018.01.006 .

Dereje, M. M.; Ji, D.; Kang, S.H.; Yang, C.; Noh, Y. Y . Effect of pre-aggregation in conjugated polymer solution on performance of diketopyrrolopyrrole-based organic field-effect transistors . Dyes Pigments , 2017 , 145 270 - 276 . DOI: 10.1016/j.dyepig.2017.06.018 http://doi.org/10.1016/j.dyepig.2017.06.018 .

Gaikwad, A. M.; Khan, Y.; Ostfeld, A. E.; Pandya, S.; Abraham, S.; Arias, A. C . Identifying orthogonal solvents for solution processed organic transistors . Org. Electron. , 2016 , 30 18 - 29 . DOI: 10.1016/j.orgel.2015.12.008 http://doi.org/10.1016/j.orgel.2015.12.008 .

Li, H.; Liu, X.; Jin, T.; Zhao, K.; Zhang, Q.; He, C.; Yang, H.; Chen, Y.; Huang, J.; Yu, X.; Han, Y . Optimizing the intercrystallite connection of a donor-acceptor conjugated semiconductor polymer by controlling the crystallization rate via temperature . Macromol. Rapid Commun. , 2022 , 43 e2200084 DOI: 10.1002/marc.202200084 http://doi.org/10.1002/marc.202200084 .

Zhao, K.; Zhang, Q.; Chen, L.; Zhang, T.; Han, Y . Nucleation and growth of P(NDI2OD-T2) nanowires via side chain ordering and backbone planarization . Macromolecules , 2021 , 54 2143 - 2154 . DOI: 10.1021/acs.macromol.0c02436 http://doi.org/10.1021/acs.macromol.0c02436 .

Hansen, C. M. in Hansen Solubility Parameters: A User's Handbook . CRC Press: Boca Raton, 2007 , p. 75.

Panzer, F.; Bassler, H.; Kohler, A . Temperature induced order-disorder transition in solutions of conjugated polymers probed by optical spectroscopy . J. Phys. Chem. Lett. , 2017 , 8 114 - 125 . DOI: 10.1021/acs.jpclett.6b01641 http://doi.org/10.1021/acs.jpclett.6b01641 .

Schroeder, B. C.; Chiu, Y. C.; Gu, X.; Zhou, Y.; Xu, J.; Lopez, J.; Lu, C.; Toney, M. F.; Bao, Z . Non-conjugated flexible linkers in semiconducting polymers: a pathway to improved processability without compromising device performance . Adv. Electron. Mater. , 2016 , 2 1600104 DOI: 10.1002/aelm.201600104 http://doi.org/10.1002/aelm.201600104 .

Zhou, Y.; Fuentes-Hernandez, C.; Shim, J.; Meyer, J.; Giordano, A. J.; Li, H.; Winget, P.; Papadopoulos, T.; Cheun, H.; Kim, J.; Fenoll, M.; Dindar, A.; Haske, W.; Najafabadi, E.; Khan, T. M.; Sojoudi, H.; Barlow, S.; Graham, S.; Bredas, J. L.; Marder, S. R.; Kahn, A.; Kippelen, B . A universal method to produce low-work function electrodes for organic electronics . Science , 2012 , 336 327 - 332 . DOI: 10.1126/science.1218829 http://doi.org/10.1126/science.1218829 .

Dong, H.; Jiang, S.; Jiang, L.; Liu, Y.; Li, H.; Hu, W.; Wang, E.; Yan, S.; Wei, Z.; Xu, W.; Gong, X . Nanowire crystals of a rigid rod conjugated polymer . J. Am. Chem. Soc. , 2009 , 131 17315 - 17320 . DOI: 10.1021/ja907015p http://doi.org/10.1021/ja907015p .

Yao, Y.; Dong, H.; Liu, F.; Russell, T. P.; Hu, W . Approaching intra- and interchain charge transport of conjugated polymers facilely by topochemical polymerized single crystals . Adv. Mater. , 2017 , 29 1701251 DOI: 10.1002/adma.201701251 http://doi.org/10.1002/adma.201701251 .

Yao, Z. F.; Li, Q. Y.; Wu, H. T.; Ding, Y. F.; Wang, Z. Y.; Lu, Y.; Wang, J. Y.; Pei, J . Building crystal structures of conjugated polymers through X-ray diffraction and molecular modeling . SmartMat , 2021 , 2 378 - 387 . DOI: 10.1002/smm2.1053 http://doi.org/10.1002/smm2.1053 .

Rivnay, J.; Noriega, R.; Kline, R. J.; Salleo, A.; Toney, M. F . Quantitative analysis of lattice disorder and crystallite size in organic semiconductor thin films . Phys. Rev. B , 2011 , 84 045203 DOI: 10.1103/PhysRevB.84.045203 http://doi.org/10.1103/PhysRevB.84.045203 .

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