Reinforcement of High Impact Polystyrene by Aramid Nanoparticle Fillers Prepared <italic style="font-style: italic">via</italic> an <italic style="font-style: italic">In situ</italic> Bottom-up Approach

Xiang-Jun Gong; Zhi-Ping Zhao; Chang-Mei Sun; Ying Zhang; Rong-Jun Qu; Ying Wang

doi:10.1007/s10118-024-3124-6

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Reinforcement of High Impact Polystyrene by Aramid Nanoparticle Fillers Prepared via an In situ Bottom-up Approach

RESEARCH ARTICLE | Updated：2024-08-06

- Reinforcement of High Impact Polystyrene by Aramid Nanoparticle Fillers Prepared via an In situ Bottom-up Approach
- Chinese Journal of Polymer Science Vol. 42, Issue 8, Pages: 1167-1176(2024)
- Affiliations：
  
  School of Chemistry and Materials Science, Ludong University, Yantai 264025, China
- Author bio：
  
  sunchangmei0535@126.com (C.M.S.)
  rongjunqu@sohu.com (R.J.Q.)
- Funds：
- DOI：10.1007/s10118-024-3124-6
  CLC：
- Published：01 August 2024，
  
  Published Online：25 April 2024，
  
  Received：09 January 2024，
  
  Revised：05 March 2024，
  
  Accepted：11 March 2024
- Accepted：
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Gong, X. J.; Zhao, Z. P.; Sun, C. M.; Zhang, Y.; Qu, R. J.; Wang, Y. Reinforcement of high impact polystyrene by aramid nanoparticle fillers prepared via an in situ bottom-up approach. Chinese J. Polym. Sci. 2024, 42, 1167–1176

Xiang-Jun Gong, Zhi-Ping Zhao, Chang-Mei Sun, et al. Reinforcement of High Impact Polystyrene by Aramid Nanoparticle Fillers Prepared via an In situ Bottom-up Approach. [J]. Chinese Journal of Polymer Science 42(8):1167-1176(2024)
Gong, X. J.; Zhao, Z. P.; Sun, C. M.; Zhang, Y.; Qu, R. J.; Wang, Y. Reinforcement of high impact polystyrene by aramid nanoparticle fillers prepared via an in situ bottom-up approach. Chinese J. Polym. Sci. 2024, 42, 1167–1176 DOI： 10.1007/s10118-024-3124-6.

Xiang-Jun Gong, Zhi-Ping Zhao, Chang-Mei Sun, et al. Reinforcement of High Impact Polystyrene by Aramid Nanoparticle Fillers Prepared via an In situ Bottom-up Approach. [J]. Chinese Journal of Polymer Science 42(8):1167-1176(2024) DOI： 10.1007/s10118-024-3124-6.

摘要

In this paper

PPTA nanoparticles were directly synthesized in HIPS matrix by in-situ polycondensation method

which not only solved the problems of easy agglomeration and difficult dispersion of nano PPTA in polymer matrix

but also significantly improved the mechanical properties of HIPS.

Abstract

In this work

aramid nanoparticles (ANPs) were prepared in dimethyl formamide (DMF) solution containing high impact polystyrene (HIPS)

via

a bottom-up approach. Transmission electron microscopy (TEM) images showed that the obtained ANPs were evenly distributed in the H

IPS matrix without any agglomeration. Chemical composition of the ANPs

i.e.

poly(

-phenyl-

-phenylenediamine) (PPTA)

was confirmed by Fourier transform infrared spectroscopy (FTIR)

X-ray photoelectron spectroscopy (XPS) and X-ray diffractometer (XRD). The ANP/HIPS composites

obtained after ethanol precipitation

were added to neat HIPS as fillers to fabricate ANP/HIPS composite sheets. The surface roughness and the glass transition temperature (

) of the sheets were characterized by atomic force microscope (AFM) and differential scanning calorimetry (DSC)

respectively. Compared with neat HIPS

the mechanical properties of the composite sheet were significantly improved

and the Young's modulus increased from 246.55 MPa to 2025.12 MPa

the tensile strength increased from 3.07 MPa to 29.76 MPa

and the toughness increased from 0.32 N/mm

to 3.92 N/mm

with an increase rate of 721%

869% and 1125%

respectively. Moreover

the thermal stability of the composites improved with the increase in ANP content.

关键词

Keywords

High impact polystyrenePPTA nanoparticleReinforceMechanical property

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Reinforcement of High Impact Polystyrene by Aramid Nanoparticle Fillers Prepared via an In situ Bottom-up Approach

DOI：10.1007/s10118-024-3124-6

摘要

Abstract

关键词

Keywords

references